ماء شبه ثقيل Semiheavy water

Semiheavy water
Spacefill model of water
Semiheavy water.svg
الأسماء
اسم أيوپاك
(2H1)Water
أسماء أخرى
Deuterium hydrogen monoxide
Deuterium hydrogen oxide, Water-d1, Water-d
المُعرِّفات
رقم CAS
3D model (JSmol)
ChEBI
ChemSpider
مرجع Gmelin 115
الخصائص
الصيغة الجزيئية H2HO or HDO
كتلة مولية 19.0214 g mol−1
المظهر Very pale blue, transparent liquid, very similar to regular water
الكثافة 1.054 g cm−3
نقطة الانصهار
نقطة الغليان
قابلية الذوبان في الماء miscible
log P −0.65
ما لم يُذكر غير ذلك، البيانات المعطاة للمواد في حالاتهم العيارية (عند 25 °س [77 °ف]، 100 kPa).
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مراجع الجدول

الماء شبه الثقيل is the result of replacing one of the protium (normal hydrogen, 1H) in normal water with deuterium (2H; or D).[1] It exists whenever there is water with 1H and 2H in the mix. This is because hydrogen atoms (1,2H) are rapidly exchanged between water molecules. Water with 50% 1H and 50% 2H, is about 50% H2HO and 25% each of H2O and 2H2O, in dynamic equilibrium.[2] In normal water, about 1 molecule in 3,200 is HDO (1H2HO) (one hydrogen in 6,400 is 2H). By comparison, heavy water D2O or 2H2O[3] occurs at a proportion of about 1 molecule in 41 million (i.e., 1 in 6,4002). This makes semiheavy water far more common than "normal" heavy water.

The freezing point of semiheavy water is close to the freezing point of heavy water at 3.81°C compared to the 3.82°C of heavy water.

الانتاج

On Earth, semiheavy water occurs naturally in normal water at a proportion of about 1 molecule in 3,200; because 1 in 6,400 hydrogen atoms in water is deuterium, which is 1 part in 3,200 by weight. HDO may be separated from normal water by distillation or electrolysis, or by various chemical exchange processes, all of which exploit a kinetic isotope effect. Partial enrichment also occurs in natural bodies of water under certain evaporation conditions.[4] (For more information about the distribution of deuterium in water, see Vienna Standard Mean Ocean Water and Hydrogen isotope biogeochemistry.)

انظر أيضاً

المراجع

  1. ^ Tashakor S (2016-09-28). "Neutronic Investigation of Semi-Heavy Water Application in Hplwr New Flow Pattern". CNL Nuclear Review (in الإنجليزية): 1–5. doi:10.12943/CNR.2016.00019.
  2. ^ Goncharuk VV, Kavitskaya AA, Romanyukina IY, Loboda OA (June 2013). "Revealing water's secrets: deuterium depleted water". Chemistry Central Journal. 7 (1): 103. doi:10.1186/1752-153X-7-103. PMC 3703265. PMID 23773696.
  3. ^ "Heavy water | chemical compound". Encyclopedia Britannica (in الإنجليزية). Retrieved 2019-04-24.
  4. ^ Craig, H.; Gordon, L. I.; Horibe, Y. (1963). "Isotopic exchange effects in the evaporation of water: 1. Low-temperature experimental results". Journal of Geophysical Research (in الإنجليزية). 68 (17): 5079–5087. Bibcode:1963JGR....68.5079C. doi:10.1029/JZ068i017p05079.

للاستزادة

قالب:Water


قالب:Chem-compound-stub