ماء شبه ثقيل Semiheavy water

(تم التحويل من Semiheavy water)
Semiheavy water
Spacefill model of water
Semiheavy water.svg
الأسماء
اسم أيوپاك
(2H1)Water
أسماء أخرى
Deuterium hydrogen monoxide
Deuterium hydrogen oxide, Water-d1, Water-d
المُعرِّفات
رقم CAS
3D model (JSmol)
ChEBI
ChemSpider
مرجع Gmelin 115
الخصائص
الصيغة الجزيئية H2HO or HDO
كتلة مولية 19.0214 g mol−1
المظهر Very pale blue, transparent liquid, very similar to regular water
الكثافة 1.054 g cm−3
نقطة الانصهار
نقطة الغليان
قابلية الذوبان في الماء miscible
log P −0.65
ما لم يُذكر غير ذلك، البيانات المعطاة للمواد في حالاتهم العيارية (عند 25 °س [77 °ف]، 100 kPa).
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مراجع الجدول

الماء شبه الثقيل is the result of replacing one of the protium (normal hydrogen, 1H) in normal water with deuterium (2H; or D).[1] It exists whenever there is water with 1H and 2H in the mix. This is because hydrogen atoms (1,2H) are rapidly exchanged between water molecules. Water with 50% 1H and 50% 2H, is about 50% H2HO and 25% each of H2O and 2H2O, in dynamic equilibrium.[2] In normal water, about 1 molecule in 3,200 is HDO (1H2HO) (one hydrogen in 6,400 is 2H). By comparison, heavy water D2O or 2H2O[3] occurs at a proportion of about 1 molecule in 41 million (i.e., 1 in 6,4002). This makes semiheavy water far more common than "normal" heavy water.

The freezing point of semiheavy water is close to the freezing point of heavy water at 3.81°C compared to the 3.82°C of heavy water.

الانتاج

On Earth, semiheavy water occurs naturally in normal water at a proportion of about 1 molecule in 3,200; because 1 in 6,400 hydrogen atoms in water is deuterium, which is 1 part in 3,200 by weight. HDO may be separated from normal water by distillation or electrolysis, or by various chemical exchange processes, all of which exploit a kinetic isotope effect. Partial enrichment also occurs in natural bodies of water under certain evaporation conditions.[4] (For more information about the distribution of deuterium in water, see Vienna Standard Mean Ocean Water and Hydrogen isotope biogeochemistry.)

انظر أيضاً

المراجع

  1. ^ Tashakor S (2016-09-28). "Neutronic Investigation of Semi-Heavy Water Application in Hplwr New Flow Pattern". CNL Nuclear Review (in الإنجليزية): 1–5. doi:10.12943/CNR.2016.00019.
  2. ^ Goncharuk VV, Kavitskaya AA, Romanyukina IY, Loboda OA (June 2013). "Revealing water's secrets: deuterium depleted water". Chemistry Central Journal. 7 (1): 103. doi:10.1186/1752-153X-7-103. PMC 3703265. PMID 23773696.
  3. ^ "Heavy water | chemical compound". Encyclopedia Britannica (in الإنجليزية). Retrieved 2019-04-24.
  4. ^ Craig, H.; Gordon, L. I.; Horibe, Y. (1963). "Isotopic exchange effects in the evaporation of water: 1. Low-temperature experimental results". Journal of Geophysical Research (in الإنجليزية). 68 (17): 5079–5087. Bibcode:1963JGR....68.5079C. doi:10.1029/JZ068i017p05079.

للاستزادة

قالب:Water


قالب:Chem-compound-stub